重质油制轻烯烃:英文 HEAVY OIL TO LIGHT OLEFINS

本书主要介绍近年来我国自主开发并广泛应用的多项催化裂化家族技术——重质油制轻烯烃技术的研究思路、开发过程及工业应用，包括反应化学、催化材料、工艺工程、技术经济评价。主要包括我国成功自主开发的多种重油制取乙烯和丙烯工艺：DCC(催化裂解)，MGG(蜡油掺炼渣油原料最大量生产汽油和液化气)，ARGG(常压渣油原料最大量生产汽油和液化气)，MIO(最大量生产异构烯烃)，MGD(最大量生产液化气和轻柴油)，CPP（重油直接制取乙烯和丙烯），RTC（重油制化学品），FDFCC（双提升管催化裂化），TMP（最大化生产丙烯）等。具体章节如下： 1. Introduction 2. Chemical Reaction Mechanism 3. Catalytic Material and Catalyst 4. DCC Process 5. CPP Process 6. RTC Process 7. FDFCC Process 8. TMP Process9. Other Processes Oriented to Market Changing 9.1 MGG and ARGG Process9.2 MGD Process9.3 MIO Process10. Chemical Engineering 11. Technologcal-Economic Evaluation 12. Perspectives

汪燮卿，中国工程院院士，中国石化石油化工科学研究院教授级高工。长期主持催化裂解（DDC）、催化裂化多产液化气和汽油（MGG）等方面的研究。研制成功具有独创性的用重质原料生产轻质烯烃和高质量汽油的新技术，并得到广泛应用；研究成功DCC－Ⅱ和以常压渣油为原料的MGG工业成套技术ARGG新工艺；研究成功符合DCC和MGG工艺要求的CRP、CIP、RMG和RAG等催化剂并实现了工业化；指导研制成功钛硅分子筛作氧化催化剂并实现工业化应用。发表专著6部，论文160余篇。


舒兴田，中国工程院院士，中国石化石油化工科学研究院教授级高工。现任石油化工科学研究院学术委员会副主任。长期从事分子筛的开发和工业应用等研究。研制出含磷和稀土、兼有二次孔的五元环结构高硅ZRP分子筛，采用沉积硅和稀土氧化物与Y型分子筛之间水热反应的独特改性方法制成SRNY分子筛；研制成功新一代超稳Y分子筛类的PSY分子筛；研制出采用模板剂在固体表面浓集并与分段晶体化结合的β分子筛，以及采用重排方法合成的HTS分子筛。发表论文60余篇。

1 Introduction  ( 001 )

2 Chemistry Reaction Mechanism  ( 012 )

2.1 Carbocation chemistry  ( 012 )

2.2 Reaction thermodynamics and kinetics  ( 017 )

2.3 Reaction mechanism of catalytic cracking of pure
hydrocarbons  ( 028 )

2.4 Reaction mechanism of heavy oil catalytic
cracking  ( 038 )

2.5 Shape selective catalysis and catalytic cracking
chemistry  ( 046 )

2.6 Summary  ( 051 )

3 Catalytic Materials and Catalysts  ( 057 )

3.1 Brief introduction of zeolites  ( 057 )

3.2 Zeolite: the active component of catalytic
cracking catalysts  ( 058 )

3.3 DCC catalyst design building blocks  ( 079 )

3.4 DCC series catalyst development  ( 082 )

4 Deep Catalytic Cracking (DCC) Process
 ( 092 )

4.1 Introduction  ( 092 )

4.2 The development of DCC process  ( 099 )

4.3 The pilot test of DCC process  ( 111 )

4.4 Industrial demo test of DCC process  ( 124 )

4.5 The introduction of the first commercial DCC unit
 ( 140 )

4.6 The introduction of a commercial MCP unit  ( 152 )

4.7 The introduction of a commercial DCC￣plus unit  ( 154 )

4.8 Overseas commercial application of DCC process  ( 165 )

4.9 The outlook for heavy oil to propylene technology
 ( 171 )

5 Catalytic Pyrolysis Process (CPP)  ( 178 )

5.1 Introduction  ( 178 )

5.2 Feed and catalyst  ( 185 )

5.3 Pilot test of CPP process  ( 188 )

5.4 Process and engineering development  ( 200 )

5.5 Industrial demo test  ( 204 )

5.6 Industrial applications of CPP technology  ( 210 )

6 RTC Process  ( 226 )

6.1 Introduction  ( 226 )

6.2 Reaction behavior of hydrotreated residue in RTC  ( 232 )

6.3 Study and design of RTC reactor  ( 237 )

6.4 The pilot research of RTC process  ( 242 )

6.5 Industrial test  ( 245 )

6.6 Commercial application  ( 255 )

7 FDFCC Process  ( 259 )

7.1 Introduction  ( 259 )

7.2 FDFCC core technology advantages and features  ( 260 )

7.3 Feedstocks and catalyst  ( 270 )

7.4 Experimental study  ( 271 )

7.5 Industrial test  ( 288 )

7.6

Industry application  ( 302 )

8

Other Processes Oriented to Market Changing

 ( 307 )

8.1 MGG and ARGG process  ( 307 )

8.2 MGD process  ( 334 )

8.3 MIO technology  ( 362 )

9 Engineering Technology of Heavy Oil to Light
Olefins Processes  ( 384 )

9.1 Engineering characteristics of heavy oil to light
olefins processes  ( 384 )

9.2 Process and engineering characteristics of
reactor￣regenerator
section  ( 392 )

9.3 Process and engineering of quench and
fractionation system  ( 408 )

9.4 Purification and separation engineering of CPP
pyrolysis gas  ( 415 )

9.5 Recovery and utilization of C2 hydrocarbons in
dry gas obtained from the heavy

oil to light olefins process  ( 426 )

9.6 Optimization of energy utilization  ( 429 )

10 Techno￣economic Evaluation  ( 439 )

10.1 Selection of evaluation scheme  ( 439 )

10.2 Basic principles, parameters and assumptions of
evaluation  ( 440 )

10.3 Analysis on techno￣economic characteristics  ( 444 )

10.4 Comprehensive analysis  ( 449 )

11 Advances and Perspectives of Light Olefins
Production from Other Pathway  ( 453 )

11.1 Oxidative coupling of methane (OCM)  ( 453 )

11.2 Ethane to ethylene: EC, EDH, and ODH  ( 456 )

11.3 Propane dehydogenation (PDH)  ( 461 )

11.4 Olefin catalytic cracking technology for
producing propylene and ethylene  ( 465 )

11.5 SNCC—extending the DCC technology towards CTC (Crude To
Chemicals) ( 476 )

11.6 CCPP: paving the way for converting crude oil to
petrochemicals  ( 479 )